The first time that Ash’s (often appearing! Gary doesn’t count) rival had an Turtle Pokemon (the second one is Tierro, but with him it was a friendly competition, while Ash and Paul presented extremely different approach to Pokemon). This torterra has an interesting character, although Ash and Paul did not like each other (mainly Ash didn’t like Paul, when he mostly did not notice Ash), he helped Ash’s Grotle when he had trouble adjusting to himself after evolving.
Below is a list of the episodes in which this Pokemon appears – the first number is the overall episode number, the second is the episode number within the sub-series, DP is Diamond & Pearl. Episode numbers according to the schedule on Bulbapedia.
506 – DP040 – Top-Down Training! – Debut (Paul mentions Torterra being his first Pokemon.)
517 – DP051 – Glory Blaze!
518 – DP052 – Smells Like Team Spirit!
566 – DP100 – Aiding the Enemy! – Team Rocket gets Torterra a “haircut”, there is also Ash’s Grotle which Paul’s Torterra helps.
593 – DP127 – Sliding Into Seventh! – Flashback.
594 – DP128 – A Pyramiding Rage! – Only as Turtwig, in Paul’s brother flashback.
597 – DP131 – Pedal to the Mettle!
598 – DP132 – Evolving Strategies!
599 – DP133 – Uncrushing Defeat! – Flashback
607 – DP141 – Challenging a Towering Figure! – Flashback
654 – DP188 – Battling a Thaw in Relations! – He is seen on the farm at Reggie, Paul’s brother.